Broiling dried chiles produces smoke that is, in effect, a light aerosolized version of pepper spray. It smells extraordinary — and it will absolutely find every sensitive airway in the room. Before the chiles go under the broiler, open every window, run the range hood on high, and ask anyone with asthma, allergies, or particularly tender lungs to step outside until the smoke clears. It’s not a crisis. It’s just the price of great mole.
Mole negro improves dramatically after 24–48 hours as the flavors meld. Make it at the start of the week, refrigerate, and use it across carnitas, enchiladas, and anything else that needs it.